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NFPA 704 Classification

1. Special notice

Code
Description
ACID Acid
ALK Alkaline
BIO Biological Hazard
COR Corrosive
CRYO Cryogenic
OX Oxidizer
POI Poisonous
RAD Radioactive
SA Simple Asphyxiant
-W- Reacts With Water
           Blank

2. Instability/Reactivity

Code
Description
0 Stable
1 Unstable If Heated
2 Violent Chemical Change
3 Stock/Heat May Detonate
4 May Detonate

3. Health

Code
Description
0 Normal Material
1 Slightly Hazardous
2 Hazardous
3 Extreme Danger
4 Deadly

4. Flammability

Code
Description
0 Will Not Burn
1 Above 200°F
2 Between 100°F and 200°F
3 Below 100°F
4 Below 73°F

 

Globally Harmonized System (GHS) for Classification and Labelling of Chemicals


1. GHS Pictograms

Code
Description
SGH01 Explosives
SGH02 Flammable Liquids
SGH03 Oxidizing Liquids
SGH04 Compressed Gases
SGH05 Corrosive
SGH06 Acute Toxicity
SGH07 Toxic, Irration
SGH08 Aspiration Hazard
SGH09 Hazardous to the Aquatic Environment


2. GHS Hazard Statements

H200 Unstable explosive
H201 Explosive; mass explosion hazard
H202 Explosive; severe projection hazard
H203 Explosive; fire, blast or projection hazard
H204 Fire or projection hazard
H205 May mass explode in fire
H206 Fire, blast projection hazard; increased risk of explosion if desensitized agent is reduced
H207 Fire or projection hazard; increased risk of explosion if desensitized agent is reduced
H208 Fire hazard; increased risk of explosion if desensitized agent is reduced
H220 Extremely flammable gas
H221 Flammable gas
H222 Extremely flammable aerosol
H223 Flammable aerosol
H224 Extremely flammable liquid and vapour
H225 Highly flammable liquid and vapour
H226 Flammable liquid and vapour
H227 Combustible liquid
H228 Flammable solid
H229 Pressurized container: may burst if heated
H230 May react explosively even in the absence of air
H231 May react explosively even in the absence of air at elevated pressure and/or temperature
H232 May ignite spontaneously if exposed to air
H240 Heating may cause an explosion
H241 Heating may cause a fire or explosion
H242 Heating may cause a fire
H250 Catches fire spontaneously if exposed to air
H251 Self-heating; may catch fire
H252 Self-heating in large quantities; may catch fire
H260 In contact with water releases flammable gases which may ignite spontaneously
H261 In contact with water releases flammable gases
H270 May cause or intensify fire; oxidizer
H271 May cause fire or explosion; strong oxidizer
H272 May intensify fire; oxidizer
H280 Contains gas under pressure; may explode if heated
H281 Contains refrigerated gas; may cause cryogenic burns or injury
H290 May be corrosive to metals
H300 Fatal if swallowed
H300 + H310 Fatal if swallowed or in contact with skin
H300 + H310 + H330 Fatal if swallowed, in contact with skin or if inhaled
H300 + H330 Fatal if swallowed or if inhaled
H301 Toxic if swallowed
H301 + H311 Toxic if swallowed or in contact with skin
H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled
H301 + H331 Toxic if swallowed or if inhaled
H302 Harmful if swallowed
H302 + H312 Harmful if swallowed or in contact with skin
H302 + H312 + H332 Harmful if swallowed, in contact with skin or if inhaled
H302 + H332 Harmful if swallowed or if inhaled
H303 May be harmful if swallowed
H303 + H313 May be harmful if swallowed or in contact with skin
H303 + H313 + H333 May be harmful if swallowed, in contact with skin or if inhaled
H303 + H333 May be harmful if swallowed or if inhaled
H304 May be fatal if swallowed and enters airways
H305 May be harmful if swallowed and enters airways
H310 Fatal in contact with skin
H310 + H330 Fatal in contact with skin or if inhaled
H311 Toxic in contact with skin
H311 + H331 Toxic in contact with skin or if inhaled
H312 Harmful in contact with skin
H312 + H332 Harmful in contact with skin or if inhaled
H313 May be harmful in contact with skin
H313 + H333 May be harmful in contact with skin or if inhaled
H314 Causes severe skin burns and eye damage
H315 Causes skin irritation
H315 + H320 Causes skin and eye irritation
H316 Causes mild skin irritation
H317 May cause an allergic skin reaction
H318 Causes serious eye damage
H319 Causes serious eye irritation
H320 Causes eye irritation
H330 Fatal if inhaled
H331 Toxic if inhaled
H332 Harmful if inhaled
H333 May be harmful if inhaled
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335 May cause respiratory irritation
H336 May cause drowsiness or dizziness
H340 May cause genetic defects (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H341 Suspected of causing genetic defects (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H350 May cause cancer (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H351 Suspected of causing cancer (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H360 May damage fertility or the unborn child (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H361 Suspected of damaging fertility or the unborn child (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H362 May cause harm to breast-fed children
H370 Causes damage to organs (or state all organs affected, if known) (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H371 May cause damage to organs (or state all organs affected, if known) (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H372 Causes damage to organs (or state all organs affected, if known) through prolonged or repeated exposure (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H373 May cause damage to organs (or state all organs affected, if known)through prolonged or repeated exposure (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H400 Very toxic to aquatic life
H401 Toxic to aquatic life
H402 Harmful to aquatic life
H410 Very toxic to aquatic life with long lasting effects
H411 Toxic to aquatic life with long lasting effects
H412 Harmful to aquatic life with long lasting effects
H413 May cause long lasting harmful effects to aquatic life
H420 Harms public health and the environment by destroying ozone in the upper atmosphere

3. GHS Precautionary Statements

P101 If medical advice is needed, have product container or label at hand
P102 Keep out of reach of children
P103 Read label before use
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P211 Do not spray on an open flame or other igntion source
P212 Avoid heating under confinement or reduction of the desensitized agent
P220 Keep away from clothing and other combustible materials
P222 Do not allow contact with air
P223 Do not allow contact with water
P230 Keep wetted with …
P231 Handle and store contents under inert gas/…
P231 + P232 Handle and store contents under inert gas/… Protect from moisture
P232 Protect from moisture
P233 Keep container tightly closed
P234 Keep only in original packaging
P235 Keep cool
P240 Ground and bond container and receiving equipment
P241 Use explosion-proof [electrical/ventilating/lighting/…] equipment
P242 Use only non-sparking tools
P243 Take action to prevent static discharges
P244 Keep valves and fittings free from oil and grease
P250 Do not subject to grinding/shock/friction/…
P251 Do not pierce or burn, even after use
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P262 Do not get in eyes, on skin, or on clothing
P263 Avoid contact during pregnancy and while nursing
P264 Wash … thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P271 Use only outdoors or in a well-ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection
P282 Wear cold insulating gloves and either face shield or eye protection
P283 Wear fire resistant or flame retardant clothing
P284 [In case of inadequate ventilation] wear respiratory protection
P301 IF SWALLOWED:
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/…
P301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor/… if you feel unwell
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P302 IF ON SKIN:
P302 + P334 IF ON SKIN: Immerse in cool water [or wrap in wet bandages]
P302 + P335 + P334 IF ON SKIN: Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages]
P302 + P352 IF ON SKIN: Wash with plenty of water…
P303 IF ON SKIN (or hair):
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]
P304 IF INHALED: P304 + P312 IF INHALED: Call a POISON CENTER/doctor/… if you feel unwell
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305 IF IN EYES:
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P306 IF ON CLOTHING:
P306 + P360 IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes
P308 IF exposed or concerned:
P308 + P311 IF exposed or concerned: Call a POISON CENTER/doctor/…
P308 + P313 IF exposed or concerned: Get medical advice/attention
P310 Immediately call a POISON CENTER/doctor/…
P311 Call a POISON CENTER/doctor/…
P312 Call a POISON CENTER/doctor/… if you feel unwell
P313 Get medical advice/attention
P314 Get medical advice/attention if you feel unwell
P315 Get immediate medical advice/attention
P320 Specific treatment is urgent (see … on this label)
P321 Specific treatment (see … on this label)
P330 Rinse mouth
P331 Do NOT induce vomiting
P332 If skin irritation occurs:
P332 + P313 If skin irritation occurs: Get medical advice/attention
P333 If skin irritation or a rash occurs:
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention
P334 Immerse in cool water [or wrap in wet bandages]
P335 Brush off loose particles from skin
P336 Thaw frosted parts with lukewarm water. Do not rub affected areas
P336 + P315 Thaw frosted parts with lukewarm water. Do not rub affected area. Get immediate medical advice/attention
P337 If eye irritation persists:
P337 + P313 If eye irritation persists: Get medical advice/attention
P338 Remove contact lenses, if present and easy to do. Continue rinsing
P340 Remove person to fresh air and keep comfortable for breathing
P342 If experiencing respiratory symptoms:
P342 + P311 If experiencing respiratory symptoms:
Call a POISON CENTER/doctor/…
P351 Rinse cautiously with water for several minutes
P352 Wash with plenty of water/…
P353 Rinse skin with water [or shower]
P360 Rinse immediately contaminated clothing and skin with plenty of water before removing clothes
P361 Take off immediately all contaminated clothing
P361 + P364 Take off immediately all contaminated clothing and wash it before reuse
P362 Take off contaminated clothing
P362 + P364 Take off contaminated clothing and wash it before reuse
P363 Wash contaminated clothing before reuse
P364 And wash it before reuse
P370 In case of fire:
P370 + P372 + P380 + P373 In case of fire: Explosion risk. Evacuate area. DO NOT fight fire when fire reaches explosives
P370 + P376 In case of fire: Stop leak if safe to do so
P370 + P378 In case of fire: Use … to extinguish
P370 + P380 + P375 In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion
P370 + P380 + P375 [+ P378] In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. [Use…to extinguish]
P371 In case of major fire and large quantities:
P371 + P380 + P375 In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion
P372 Explosion risk
P373 DO NOT fight fire when fire reaches explosives
P375 Fight fire remotely due to the risk of explosion
P376 Stop leak if safe to do so
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely
P378 Use … to extinguish
P380 Evacuate area
P381 In case of leakage, eliminate all ignition sources
P390 Absorb spillage to prevent material damage
P391 Collect spillage
P401 Store in accordance with…
P402 Store in a dry place
P402 + P404 Store in a dry place. Store in a closed container
P403 Store in a well-ventilated place
P403 + P233 Store in a well-ventilated place. Keep container tightly closed
P403 + P235 Store in a well-ventilated place. Keep cool
P404 Store in a closed container
P405 Store locked up
P406 Store in a corrosion resistant/… container with a resistant inner liner
P407 Maintain air gap between stacks or pallets
P410 Protect from sunlight
P410 + P403 Protect from sunlight. Store in a well-ventilated place
P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F
P411 Store at temperatures not exceeding … °C/… °F
P412 Do not expose to temperatures exceeding 50 °C/122 °F
P413 Store bulk masses greater than … kg/…lbs at temperatures not exceeding …°C/…°F
P420 Store separately
P501 Dispose of contents/container to …
P502 Refer to manufacturer or supplier for information on recovery or recycling

4. Country Specific Hazard Statements

EUH001 Explosive when dry
EUH006 Explosive with or without contact with air
EUH014 Reacts violently with water
EUH018 In use may form flammable/explosive vapour-air mixture
EUH019 May form explosive peroxides
EUH029 Contact with water liberates toxic gas
EUH031 Contact with acids liberates toxic gas
EUH032 Contact with acids liberates very toxic gas
EUH044 Risk of explosion if heated under confinement
EUH066 Repeated exposure may cause skin dryness or cracking
EUH070 Toxic by eye contact
EUH071 Corrosive to the respiratory tract
EUH201 Contains lead. Should not be used on surfaces liable to be chewed or sucked by children.
EUH201A Warning! Contains lead.
EUH202 Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children.
EUH203 Contains chromium (VI). May produce an allergic reaction.
EUH204 Contains isocyanates. May produce an allergic reaction.
EUH205 Contains epoxy constituents. May produce an allergic reaction.
EUH206 Warning! Do not use together with other products. May release dangerous gases (chlorine).
EUH207 Warning! Contains cadmium. Dangerous fumes are formed during use. See information supplied by the manufacturer. Comply with the safety instructions.
EUH208 Contains (name of sensitising substance). May produce an allergic reaction.
EUH209 Can become highly flammable in use.
EUH209A Can become flammable in use.
EUH210 Safety data sheet available on request.
EUH401 To avoid risks to human health and the environment, comply with the instructions for use.